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Hexamethylene triperoxide diamine
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Hexamethylene triperoxide diamine : ウィキペディア英語版
Hexamethylene triperoxide diamine

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Hexamethylene triperoxide diamine (HMTD) is a high explosive organic compound. The theorized structure lent itself well to acting as an initiating, or primary explosive. While still quite sensitive to shock and friction, it was relatively stable compared to other initiating explosives of the time, such as mercury fulminate, and proved to be relatively inexpensive and easy to synthesise. As such, it was quickly taken up as a primary explosive in mining applications.〔Taylor, C. A.; Rinkenbach, W. H. ''Army Ordnance'' 1924. ''5'', 463–466〕 However, it has since been superseded by even more stable compounds such as tetryl.
==Preparation and structure==
First synthesised in 1885 by Legler, HMTD may be prepared by the reaction of an aqueous solution of hydrogen peroxide and hexamine in the presence of citric acid or dilute sulfuric acid as a catalyst.
The molecule adopts a cage-like structure.

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